Benzaldehyde dimethyl acetal 99% Synonym: α,α-Dimethoxytoluene CAS Number 1125-88-8. benzaldehyde (bĕnzăl`dəhīd) or benzenecarbonal (bĕn'zēnkär`bənəl), C 6 H 5 CHO, colorless liquid aldehyde aldehyde [alcohol + New Lat. Soluble in ethanol, diethyl ether, acetone, benzene, carbon tetrachloride.
METAPHENOXY BENZALDEHYDE is a pesticide intermediate to manufacture of synthetic Pyrethroid insecticides. Linear Formula C 6 H 5 CH(OCH 3) 2. Part of Springer Nature. Fig. benzene ring is non polar and water is a polar solvent. This work is financially supported by the Project Funded by the Excellent Specialties Program Development of Jiangsu Higher Education Institutions, Jiangsu Provincial Department of Technology (BY2016066-07), and Jiangsu Provincial Department of Technology (BY 2015058-03). : Comment on “Measurement and correlation of solubilities of (z)-2-(2-aminothiazol-4-yl)-2-methoxyiminoacetic acid in different pure solvents and binary mixtures of water + (ethanol, methanol, or glycol)”. https://doi.org/10.1007/s10953-017-0629-4. 49, 4708–4712 (2008), Chen, G.W., Chen, Y.Z., Han, M.: Synthesis method of p-methylsulfonyl benzaldehyde. Eng. Reviewers, Librarians CN Patent 103,360,287, 23 Oct 2013, Han, Z.H. Li, W., Liu, M., Liu, L. et al. dehydrogenatus=dehydrogenated], any of a class of organic compounds that contain the carbonyl group, , and in which the carbonyl group is bonded to at least one hydrogen; the general formula for an aldehyde is RCHO, where R is hydrogen The solid was washed with chloroform and ethanol and the washings were added to the original filtrate, the solvent evaporated and the residue distilled to give the benzaldehyde. J. Chem. 18, 25–38 (1984), Apelblat, A., Manzurola, E.: Solubilities of o-acetylsalicylic, 4-aminosalicylic, 3,5-dinitrosalicylic, and p-toluic acid, and magnesium-dl-aspartate in water from T = (278 to 348) K. J. Chem. RSC Adv. Solubility Measurement and the Correlation of 1-Naphthaleneacetic Acid in Pure and Methanol + Water Binary Solvents from T = (278.25 to 323.55) K. Journal of Chemical & Engineering Data 2017, 62 (4) , 1292-1301. Find more information about Crossref citation counts. CN Patent 101265,222, 17 Sept 2008, Wang, Y.Q., Li, S.L., Sun, L., Zhang, X.X., Xu, W.L. Besides, it is sometimes called benzenecarboxaldehyde, phenylmethanal, or benzoic aldehyde. Antimicrob. & Account Managers, For All of the selected models provided good representation of the experimental solubilities. Benzaldehyde definition is - a colorless nontoxic aromatic liquid C6H5CHO found in essential oils (as in peach kernels) and used in flavoring and perfumery, in pharmaceuticals, and in synthesis of dyes. Besides, it is sometimes called benzenecarboxaldehyde, phenylmethanal, or benzoic aldehyde. It is a colorless liquid aldehyde with a characteristic almond odor. The binary solid–liquid phase equilibrium for 4-(methylsulfonyl)benzaldehyde in methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, acetone, acetonitrile, toluene, and acetic acid were studied experimentally within the temperatures range from (283.15 to 318.15) K under 101.3 kPa by using a static equilibrium method. Benzaldehyde: The auto-ignition of benzaldehyde occurs at 192°C. The solubilities of 4-(methylsulfonyl)benzaldehyde in the binary mixed solvents acetonitrile + methanol, acetonitrile + ethanol and acetonitrile + isopropanol were determined experimentally using an isothermal dissolution equilibrium method within the temperature range from 283.15 to 318.15 K under atmospheric pressure. CRC Press LLC, Boca Raton: FL 2014-2015, p. 3-98 . This is a preview of subscription content, log in to check access. https://doi.org/10.1007/s10953-017-0629-4, DOI: https://doi.org/10.1007/s10953-017-0629-4, Over 10 million scientific documents at your fingertips, Not logged in The reaction is carried out by adding a mixture of two parts benzaldehyde and one part acetone to an aqueous ethanol solution of NaOH. Air sensitive: EXTERNAL LINKS & GENERAL DESCRIPTION. Freely soluble in water; soluble in alcohol, in methanol, and in glacial acetic acid, the solution in the organic solvents usually showing some insoluble residue; insoluble in acetone, in chloroform, and in ether. Table 3 Hydrocarbon Solubility in Methanol Table 3 ^ Solubility of benzaldehyde in methanol ^ Friedrich Brühne and Elaine Wright “Benzaldehyde” in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. •benzaldehyde is commercially available in two grades. Benzylideneacetone is the organic compound described by the formula C 6 H 5 CH=CHC(O)CH 3.Although both cis- and trans-isomers are possible for the α,β-unsaturated ketone, only the trans isomer is observed.Its original preparation demonstrated the scope of condensation reactions to construct new, complex organic compounds. Units of solubility are given in grams per 100 grams of solvent (g/100 g). : Solubility determination and thermodynamic models for dehydroepiandrosterone acetate in mixed solvents of (ethyl acetate + methanol), (ethyl acetate + ethanol) and (ethyl acetate + isopropanol). The solvent, aqueous ethanol, also favors the formation of dibenzalacetone. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. 17, 5369–5373 (2009), Tabata, M., Moriyama, K., Togo, H.: One-pot transformation of methylarenes into aromatic aldehydes under metal-free conditions. The compound was first isolated in 1803 by a French … *Please select more than one item to compare Values for relative polarity, eluant strength, threshold limits and vapor pressure have been extracted from: Christian Reichardt, Solvents and Solvent Effects in Organic Chemistry, Wiley-VCH Publishers, 3rd ed., 2003. J. Pharm. Haynes, W.M. It is found that the extent of solubilization strongly depends on the solute hydrphobicity and the ethanol concentration in the solvent mixture. This article is cited by Wanxin Li, Meiling Liu, Li Liu, Yang Cong, Hongkun Zhao. With the increase in temperature, the solubility of 4-(methylsulfonyl)benzaldehyde in these solvents increased. CN Patent 103,058,899, 24 Apr 2013, Lou, X.C. J Solution Chem 46, 1131–1151 (2017). The solubility values from high to low obeyed the following order in different solvents: acetone > acetonitrile > acetic acid > methanol > ethanol > toluene > 1-butanol > 1-propanol > 2-propanol. Benzaldehyde: Colorless, strongly refractive liquid, having an odor resembling that of bitter almond oil, and having a burning, aromatic taste. Solubility studies were performed for pure drug, physical mixtures and solid dispersion from both hot melt method as well as solvent evaporation method 19. : Method for preparing methylsulfonyl benzaldehyde and methylsulfonylbenzoic acid. As a bonus, potassium permanganate is reduced to MnO2, which can also oxidize benzyl alcohol, so it's important to take this … Is hygroscopic. Search. Journal of Solution Chemistry Get article recommendations from ACS based on references in your Mendeley library. The values in the table below except as noted have been extracted from online and hardbound compilations . MDL number MFCD00008491. : Process for preparing p-methylsulfonylbenzaldehyde. : Method for synthesis of 4-(methylsulfonyl)-benzaldehyde. It formed two separate layers because it was an immiscible liquid. : Handbook of Organic Solvent Properties. Miscible with alcohol, with ether, and with fixed and volatile oils. Amoled, London (1996), Jouyban, A., Martinez, F., Acree Jr., W.E. Wikipedia Linking. The solubility of potassium carbonate in methanol and the acid−base interaction of these compounds with each other have been considered. H azards. Synlett 18, 2771–2774 (2010), Article  Data 57, 1344–1346 (2012), Vahdati, S., Shayanfar, A., Hanaee, J., Martínez, F., Acree Jr., W.E., Jouyban, A.: Solubility of carvedilol in ethanol + propylene glycol mixtures at various temperatures. (NTP, 1992) CAMEO Chemicals. : Combined production method for substituted benzaldehyde, substituted benzyl alcohol and substituted benzoic acid. Contents. EP Patent 1,785,414, 16 May 2007, Chen, J.M., Zeng, X.M., Zhdankin, V.V. Benzaldehyde, 4-chloro-Benzaldehyde, p-chloro-More... Molecular Weight: 140.56 g/mol. 1.571 - 1.574 : FLASH POINT: 116 C. STABILITY: Stable under ordinary conditions. Eur. Soluble in methanol;soluble in water; sparingly soluble in water at 80°. 2005-03-26. Slightly soluble Solubility: Methanol: 0.1 g/mL Hazards Safety data sheet: MSDS at Sigma Aldrich : Describing solubility of polymorphs in mixed solvents by CNIBS/R-K equation. Create . The log–linear solubilization model was applied to the experimental solubility data of 109 organic compounds in ethanol/water mixtures. Benzaldehyde, 4-nitro-p-Formylnitrobenzene. : Non-linear van’t Hoff solubility-temperature plots and their pharmaceutical interpretation.